Defect selective etching of gaasyp1 y photovoltaic materials

Rapid and accurate threading dislocation density (TDD) characterization of direct-gap GaAsyP1−y photovoltaic materials using molten KOH defect selective etching (DSE) is demonstrated. TDDs measured.
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Direct bandgap photoluminescence from n-type indirect GaInP

3 Department of Materials Science and Engineering, Massachusetts Institute of Technology, Massachusetts 02139, Selective defect etching was used to estimate the etch pit density J. Faucher, and M. L. Lee, "Defect selective etching of GaAsyP1–y photovoltaic materials," J. Cryst. Growth 404, 140–145 (2014).

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[PDF] External Quantum Efficiency modeling of GaAs

Nov 8, 2017· A method is reported in order to determine an upper bound for the Threading Dislocation (TD) density in experimental GaAs solar cells grown lattice-mismatched on Si. The method is based on the modeling of the devices'' External Quantum Efficiency (EQE), using the classic drift-diffusion model, or Hovel model. The model is fitted to experimental EQE

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Defect-Selective Etching of Semiconductors | SpringerLink

In the present chapter we first briefly consider mechanisms for the etching of semiconductors (Sect. 43.1) and relate these principles to methods for controlling surface morphology and revealing defects (Sect. 43.2).Section 43.3 describes in some detail defect-sensitive etching methods. Results are presented for the classical (orthodox) method used for revealing

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Defect selective etching of GaAsyP1−y photovoltaic materials

GaAsyP1-y anion-sublattice compositionally graded buffers and device structures were grown directly on Si(100) substrates by way of a high-quality GaP integration layer, yielding GaAsP

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Material-selective etching of InP and an InGaAsP alloy

papers concentrates on etching of crystal defects. These papers are often based on the A-B etch [1] or H-etch [2] or combinations and variations thereof. Some of the more recent papers on defect etching are by Thiel and Barns [3], Kotani et al. [4] and Brown etal. [5]. This.group is obviously

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Fabrication and Characterization of Black GaAs Nanoarrays via ICP Etching

Jan 21, 2021· Owing to its unique optical properties, light-trapping structure plays a more and more important role in photovoltaic devices [].At present, researchers have developed all kinds of nanostructures as light-trapping structures to increase light absorption in photovoltaics, while most of them were performed on Si substrate [2,3,4,5,6].III–V compound semiconductor

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Characterization of vapor grown (001) GaAs1−xPx layers by

Dec 1, 1975· Rapid and accurate threading dislocation density (TDD) characterization of direct-gap GaAs y P 1−y photovoltaic materials using molten KOH defect selective etching (DSE) is

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Point defect engineering in thin-film solar cells

Jun 22, 2018· Control of defect processes in photovoltaic materials is essential for realizing high-efficiency solar cells and related optoelectronic devices. Native defects and extrinsic dopants tune the Fermi

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Defect selective etching of GaAs>y>P>1-y>photovoltaic materials

Rapid and accurate threading dislocation density (TDD) characterization of direct-gap GaAs y P 1-y photovoltaic materials using molten KOH defect selective etching (DSE) is demonstrated.

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Nonselective etching of As and P based III‒V solar cell

Jul 1, 2021· It is essential to know the etching mechanisms to understand and predict material-selective etching. The chapter also discusses the resulting macroscopic (that is, at single crystal faces) as well

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Joseph FAUCHER | Brown University, Rhode Island

Threading Dislocation Density Characterization in III-V Photovoltaic Materials by Electron Channeling Contrast Imaging. Article. Defect selective etching of GaAs P1− photovoltaic materials

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Direct bandgap photoluminescence from n-type indirect GaInP

Selective defect etching was used to estimate the etch pit density (EPD) of the Ga x In 1 − x P samples. The selective etching was carried out by pouring concentrated liquid H 3 PO 4 (85

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Extended Defects in SiC: Selective Etching and Raman

SiC; the etch depth of the perfect SiC matrix was 100 nm. These defects are not observed on polished surfaces before etching. Some hexagonal defects, such as the one indicated by the arrow, show complex morphology. A magnied view of the boundary of this non-homogeneously etched area is shown in Fig. 1b. The etch depth prole along the y–y'' line

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Threading dislocation density characterization in III–V photovoltaic

DOI: 10.1016/J.JCRYSGRO.2016.08.015 Corpus ID: 99891786; Threading dislocation density characterization in III–V photovoltaic materials by electron channeling contrast imaging

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Characterization of vapor grown (001) GaAs1−xPx layers by selective

Dec 1, 1975· Rapid and accurate threading dislocation density (TDD) characterization of direct-gap GaAs y P 1−y photovoltaic materials using molten KOH defect selective etching (DSE) is demonstrated. TDDs measured using molten KOH DSE show close agreement with those from both electron beam-induced current mapping and planar view transmission electron

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Comparison of compressive and tensile relaxed

Mar 1, 2010· Defect selective etching of GaAs P1− photovoltaic materials to InP, for the expansion of the palette of accessible photovoltaic materials is presented. and a high-temperature GaAsyP1−y

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Extended Defects in SiC: Selective Etching and Raman Study

Feb 8, 2023· Controlling the electrical properties of SiC requires knowledge of the nature and properties of extended defects. We have employed orthodox defect-selective etching and photo-etching methods to reveal typical and new structural defects in commercial SiC wafers. For photo-etching, the etch rate increases as the free carrier concentration decreases. The etch rate can

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Improvement the InAs, InSb, GaAs and GaSb surface state by nanoscale

Apr 1, 2021· where y—etching rate, X 1, X 2, X 3 —the concentration of etchant components in the solution ((NH 4) 2 Cr 2 O 7, HBr and EG, accordingly), k 1 k 15 —parameters of the model (Cornell 1986).. The dependence of the etch rate on the modifier concentration was considered for the range 0–95 vol.% CH 2 (OH)CH 2 (OH).. Etch rate was estimated by the electronic

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Etch Pit Observation of Very Thin {001}-GaAs Layer by Molten KOH

The etching rate on a {001} plane of GaAs in molten KOH as the etchant is examined in order to reveal etch pits corresponding to dislocations for thin GaAs layers. The mean etching rates were 0.083 µm/min. and 0.98 µm/min. at 300°C and 350°C, respectively. It was found that the etching thickness of about 0.3 µm was sufficient to reveal the dislocation structure.

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Toward metamorphic multijunction GaAsP/Si photovoltaics grown

Prototype GaAsP solar cell test devices grown on anion-sublattice step-graded GaAs y P 1-y buffers on early-stage GaP/Si substrates show good preliminary performance characteristics

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(PDF) External Quantum Efficiency modeling of GaAs solar

Nov 8, 2017· III – V photovoltaic materials by electro n channeling . contrast imaging," J. Crys. Growth 2016; Defect selective etching of GaAs P1− photovoltaic materials. Article. Oct 2014;

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Defects in wide band-gap semiconductors: selective etching and

Jul 15, 2004· Two approaches to defect-selective etching used for revealing and analysis of defects in GaN and SiC are described and critically evaluated. J. L. Weyher, C. Frigeri, S. Müller, in Microprobe characterization of optoelectronic materials, edited by J. Jimenez, (Taylor and Francis, New York, London, 2003), p. 595 [33] Nowak, G. et al., J

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Defect-selective dry etching for quick and easy probing of

Feb 9, 2018· In this study, we demonstrate a new method to selectively etch the point defects or the boundaries of as-grown hexagonal boron nitride (hBN) films and flakes in situ on copper substrates using hydrogen and argon gases. The initial quality of the chemical vapor deposition-grown hBN films and flakes was confirmed by UV–vis absorption spectroscopy, atomic force

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Dislocation Etch Pits in Single Crystal GaAs

Semantic Scholar extracted view of "Dislocation Etch Pits in Single Crystal GaAs" by J. Grabmaier et al. Physics, Materials Science; Physica Status Solidi B-basic Solid State Physics; View via Publisher. Save to Library Save. Create Alert Alert. Cite. Share. 78

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Theory of electron-beam-induced current and

May 1, 1994· THEORETICAL FUNDAMENTALS AND EXPERIMENTAL MATERIALS AND DEFECT STUDIES USING QUANTITATIVE SCANNING ELECTRON MICROSCOPY- CATHODOLUMINESCENCE/ELECTRON BEAM INDUCED CURRENT ON COMPOUND SEMICONDUCTORS. Defect selective etching of GaAsyP1−y photovoltaic materials. K. N.

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Effects of normal load and etching time on current evolution of

Jan 1, 2020· The process of the scratch-induced selective etching in H 2 SO 4 /H 2 O 2 /H 2 O solution. With an AFM, two scanning modes, i.e. line and area scanning, were used for scratching on GaAs surface, and then the scanned surface was etched in the mixed solution. AFM images show the scanned GaAs surface before and after selective etching.

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Different Etch Pit Shapes Revealed by Molten KOH Etching on

It is found that the etch pits revealed by molten KOH etching on the (001) GaAs surface have definitely different shapes depending on the Burgers vectors of the dislocations. The round hexagonal etch pit corresponds to a dislocation with Burgers vector of ½a〈101〉 inclined to the (001) plane, while the small round square etch pit corresponds to a dislocation with Burgers

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1453 43. Defect-Selective Etching of Semiconductors Defect

These materials are characterized by very high chemical resistance to the majority of the known acid-based etching systems, show strong Defect-Selective Etching of Semiconductors 43.1 Wet Etching of Semiconductors: Mechanisms 1455 hv V I WE RE CE Fig.43.1 A schematic view of a three-electrode elec-

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Etching of two-dimensional materials

Jan 1, 2021· In addition to the outer circumference of 2D islands, the evolution of an etched hole at the center of a 2D crystal is found to be similar to the growth process of a 2D single-crystal island, for example, a hole in a graphene island has a hexagonal shape with straight ZZ edges and sharp vertices during the whole etching process and the shape of a hole in hBN or GaSe

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Defect-Selective Etching of Semiconductors | Request PDF

Jan 1, 2010· During electroless and galvanic etching (for the detailed description of defect-selective etching methods dependent on the availability of charge carriers for surface reactions, see ref. 13

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Defect selective etching of GaAsyP1−y photovoltaic materials

Rapid and accurate threading dislocation density (TDD) characterization of direct-gap GaAs y P 1−y photovoltaic materials using molten KOH defect selective etching (DSE) is demonstrated. TDDs measured using molten KOH DSE show close agreement with those from both electron beam-induced current mapping and planar view transmission electron microscopy, provided

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Towards high efficiency GaAsP solar cells on (001) GaP/Si

Oct 15, 2014· Following our previously-established methodology for the growth of defect-free GaP on Si(100) substrates and demonstrations of heteroepitaxially integrated III-V-on-Si

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Defect selective etching of GaAsyP1−y photovoltaic materials

Rapid and accurate threading dislocation density (TDD) characterization of direct-gap GaAs y P 1−y photovoltaic materials using molten KOH defect selective etching (DSE) is demonstrated.

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Defect selective etching of GaAs P1− photovoltaic materials

Oct 1, 2014· Prototype 1.75-eV GaAsP solar cell test devices grown on GaAsyP1-y/Si buffers show good preliminary performance characteristics and offer great promise for future high

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Metamorphic growth of 0.1 eV InAsSb on InAs/GaAs

Jun 30, 2023· Metamorphic growth of InAsSb layers on GaAs substrate can solve this limitation and allow cost-competitiveness compared to the high-cost substrates such as GaSb and InAs [4], [5], [6].Early attempts to do this involved the direct growth of the InAsSb layer on a GaAs substrate, and more recently, the use of a single intermediate InSb layer without any strain

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GaAsP solar cells on GaP/Si with low threading dislocation density

Jul 22, 2016· Solar Energy Materials and Solar Cells. 2019; 33. PDF. Defect selective etching of GaAsyP1−y photovoltaic materials. K. N. Yaung S. Tomasulo J. R. Lang J. Faucher M. Lee. Materials Science, Physics. 2014; 14. Save. 40.8% efficient inverted triple-junction solar cell with two independently metamorphic junctions.

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(PDF) Study of HCl and Secco Defect Etching for

Aug 1, 2007· A defect selective wet chemical etching technique that allows accurate determination of etch pit density (EPD) in thin Germanium (Ge) layers is described. The effect is achieved by using chromium

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Guide to references on III–V semiconductor chemical etching

The notes include data on materials, etch rates and specific etch conditions when possible. material selective etchants, defect revealing etchants, profile etching; Ref. (Notten, P.H.L., 1993) III–V semiconductor etchant review: gives pre-1962

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About Defect selective etching of gaasyp1 y photovoltaic materials

About Defect selective etching of gaasyp1 y photovoltaic materials

Rapid and accurate threading dislocation density (TDD) characterization of direct-gap GaAsyP1−y photovoltaic materials using molten KOH defect selective etching (DSE) is demonstrated. TDDs measured.

••Accurate TDD quantification is important for metamorphic.

The integration of a highly efficient GaAsyP1−y solar cell on Si has been an attractive concept to surpass the theoretical limits of a single junction Si device for years [1], [2], [3].

All samples and solar cells were grown by molecular beam epitaxy and fabricated as previously reported [8], [16], [18], [40]. After growth, the compositions of buffer and device laye.

3.1. Molten KOH GaAsyP1−y bulk etch ratesMolten KOH forms etch pits in GaAsyP1−y with pronounced asymmetry and faceting, resembling.

Molten KOH DSE is demonstrated as a rapid (5–7 min typical etch time) and accurate method to quantify TDD over large areas (>105 µm2) of direct-bandgap GaAsyP1−.

We gratefully acknowledge funding from the NSF CAREER program (Grant no. DMR-09559616). K.N.Y. was supported by the Singapore Energy Innovation Programme Office for a.

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