About Lithium nickel cobalt aluminium oxide battery
The lithium nickel cobalt aluminium oxides (abbreviated as Li-NCA, LNCA, or NCA) are a group of mixed metal oxides. Some of them are important due to their application in lithium ion batteries. NCAs are used as active material in the positive electrode (which is the cathode when the battery is discharged).
The usable charge storage capacity of NCA is about 180 to 200 mAh/g.This is well below the theoretical values; for LiNi0.8Co0.15Al0.05O2 this is 279 mAh/g.However, the capacity of NCA is significantly higher.
The main producers of NCA and their market shares in 2015 werewith 58%, Toda Kogyo (BASF) with 16%.
NCAs LiNixCoyAlzO2 with x ≥ 0.8 are called nickel rich;those compounds are the most important variants of the substance class. The nickel-rich variants are also low in cobalt.
To make NCA more resistant, in particular for batteries that need to operate at temperatures above 50 °C, the NCA active material is usually coated. The coatings demonstrated in research may comprise fluorides such asAlF3, crystalline oxides.
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